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Triplet state time-resolved Raman investigation of biphenyl in the ultraviolet

✍ Scribed by G. Buntinx; A. Benbouazza; O. Poizat; V. Guichard

Publisher: Elsevier Science
Year: 1988
Tongue: English
Weight: 489 KB
Volume: 153
Category: Article
ISSN: 0009-2614
DOI: 10.1016/0009-2614(88)80141-6

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✦ Synopsis

Time-resolved resonance Raman spectra of the first triplet state of biphenyl derivatives are reported in the range 300-1800 cm-'. Convincing assignments and satisfactory correlation with the ground-state assignments are proposed. The DZh planar quinoidal character of T, biphenyl is shown by various characteristic spectral features which provide a fingerprint for this type of distortion.

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