The rate constants for oxygen quenching in benzene solution of the triplet states of several organic compounds with relatively high triplet energies have been measured in laser photolye> ar,.l pulse radiolysis experiments. The previously obscrvcd trend for aromatic hydrocarbons where the quenching r
β¦ LIBER β¦
Triplet state formation in the quenching of fluorescence by molecular oxygen
β Scribed by R. Potashnik; C.R. Goldschmidt; M. Ottolenghi
- Publisher
- Elsevier Science
- Year
- 1971
- Tongue
- English
- Weight
- 229 KB
- Volume
- 9
- Category
- Article
- ISSN
- 0009-2614
No coin nor oath required. For personal study only.
β¦ Synopsis
pulsed nitrogen laser is appiied for studying the quenching of aromatic hydrocarbons fluorescence by oxygen.
In non-polar solvents the process induces intersystem crossing to the triplet state with a quantum yield of unity. Effects of solvent polarity suggest that the interaction between Sl and O2(3Xi). leading to Tl, is charge-transfer in nature.
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