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Triplet state formation in the quenching of fluorescence by molecular oxygen

✍ Scribed by R. Potashnik; C.R. Goldschmidt; M. Ottolenghi


Publisher
Elsevier Science
Year
1971
Tongue
English
Weight
229 KB
Volume
9
Category
Article
ISSN
0009-2614

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✦ Synopsis


pulsed nitrogen laser is appiied for studying the quenching of aromatic hydrocarbons fluorescence by oxygen.

In non-polar solvents the process induces intersystem crossing to the triplet state with a quantum yield of unity. Effects of solvent polarity suggest that the interaction between Sl and O2(3Xi). leading to Tl, is charge-transfer in nature.


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Quenching of triplet states by molecular
✍ A. Garner; F. Wilkinson πŸ“‚ Article πŸ“… 1977 πŸ› Elsevier Science 🌐 English βš– 318 KB

The rate constants for oxygen quenching in benzene solution of the triplet states of several organic compounds with relatively high triplet energies have been measured in laser photolye> ar,.l pulse radiolysis experiments. The previously obscrvcd trend for aromatic hydrocarbons where the quenching r