Triplet state and dynamics of photoexcited C70
โ Scribed by Levanon, Haim; Meiklyar, Vladimir; Michaeli, Shalom; Gamliel, Dan
- Book ID
- 125886132
- Publisher
- American Chemical Society
- Year
- 1993
- Tongue
- English
- Weight
- 705 KB
- Volume
- 115
- Category
- Article
- ISSN
- 0002-7863
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The triplet state Raman spectra of C6O and C7o in toluene were obtained using the pump/probe technique. For C6o, new bands at 1461 and 1475 cm-1 appeared around 1470 cm-1 in the triplet state. The Raman peaks at 1448 and 1368 cm-1 for C7o shifted to lower frequencies due to the increase in antibondi
We report on the observation of two different triplet states in photoexcited C, fullerene molecules. The following fine structure parameters were determined from spectral fits to the triplet powder spectrum: IDI [=0.0117 cm-' (12.5 mT), lJ&l=O.O014 cm-' (1.5 mT) and / D2j ~0.0047 cm-' (5 mT), l&l =O