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Triplet ( S = 1) Ground State Aminyl Diradical

✍ Scribed by Rajca, Andrzej; Shiraishi, Kouichi; Pink, Maren; Rajca, Suchada


Book ID
126835624
Publisher
American Chemical Society
Year
2007
Tongue
English
Weight
84 KB
Volume
129
Category
Article
ISSN
0002-7863

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Novel spin-polarized TTF donors affordin
✍ Jotaro Nakazaki; Michio M. Matsushita; Akira Izuoka; Tadashi Sugawara πŸ“‚ Article πŸ“… 1999 πŸ› Elsevier Science 🌐 French βš– 259 KB

The concept of "spin-polasized" donor was successfully extended to TI'F-besed donor radicals. A series of TI'P derivatives carrying a phenyl nitronyl nitroxide group were prepared, and they turned out to afford ground state triplet cation diradicals through one-electron oxidation. Such "spin-polariz