The corresponding epoxides were isolated in excellent yields via oxygen transfer by dimethyldioxirane ( as acetone solution) . ## a&Unsaturated* ketones and esters are difficult to epoxidixe by peracid or metal-catalyzed methods. The use of
Triplet energies of α,β-unsaturated ketones and esters
✍ Scribed by Alan C. Weedon; David F. Wong
- Publisher
- Elsevier Science
- Year
- 1987
- Weight
- 811 KB
- Volume
- 38
- Category
- Article
- ISSN
- 0047-2670
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## Abstract For Abstract see ChemInform Abstract in Full Text.
The photochemistry of b,g-unsaturated ketones has been a topic of great interest to organic photochemists for many years. [1] The results of studies in this area show that these substances undergo a 1,3-acyl migration on direct irradiation and an oxa-di-p-methane (ODPM) rearrangement in the presence
The photochemistry of b,g-unsaturated ketones has been a topic of great interest to organic photochemists for many years. [1] The results of studies in this area show that these substances undergo a 1,3-acyl migration on direct irradiation and an oxa-di-p-methane (ODPM) rearrangement in the presence