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Triple-bonded boron opens new chemical world

✍ Scribed by Grossman, Lisa

Book ID
123557700
Publisher
Reed Business
Year
2012
Tongue
English
Weight
262 KB
Volume
214
Category
Article
ISSN
0262-4079

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Isotope-induced chemical shifts 2Ξ”10/11B
Isotope-induced chemical shifts 2Ξ”10/11B(29Si) in alkenylsilanes containing three- and four-coordinate boron. A new tool for studying weak intramolecular boron–element bonds
✍ Bernd Wrackmeyer; Oleg L. Tok πŸ“‚ Article πŸ“… 2002 πŸ› John Wiley and Sons 🌐 English βš– 150 KB

## Abstract Numerous alkenylsilanes with silyl and boryl groups in __cis__ ‐positions at the Cο£ΎC bond were studied for the first time by ^29^Si NMR with regard to isotope‐induced chemical shifts Ξ”^10/11^B(^29^Si). Such effects are transmitted across an Siβ€”Xβ€”B bridge (X = H, OR, SR, Cl) most efficie