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Triphenylphosphine/Dichloroselenurane: A New Reagent for a Selective Conversion of Alcohols into Alkyl Chlorides

✍ Scribed by Drabowicz, Józef; Luczak, Jerzy; Mikolajczyk, Marian

Book ID
120470972
Publisher
American Chemical Society
Year
1998
Tongue
English
Weight
128 KB
Volume
63
Category
Article
ISSN
0022-3263

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Hexachloroacetone/triphenylphosphine: A
Hexachloroacetone/triphenylphosphine: A reagent for the regio- and stereoselective conversion of allylic alcohols into chlorides
✍ Ronald M. Magid; O.Stanley Fruchey; William L. Johnson 📂 Article 📅 1977 🏛 Elsevier Science 🌐 French ⚖ 247 KB

The preparation of an allylic halide from the alcohol in a regio-and stereospecifically predictable fashion has been of concern to synthetic and mechanistic organic chemists. Numerous methods (of varying generality) have been developed, among which are the following: (a) reaction with conventional