Trimethylsilylpotassium. Deoxygenation of epoxides with inversion of stereochemistry
β Scribed by Dervan, Peter B.; Shippey, Michael A.
- Book ID
- 127090963
- Publisher
- American Chemical Society
- Year
- 1976
- Tongue
- English
- Weight
- 361 KB
- Volume
- 98
- Category
- Article
- ISSN
- 0002-7863
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π SIMILAR VOLUMES
We have shown thatatmiccarbonis producedinthe themal decaupositionof S-tetrazoyl diaztiun chloride (A).lSz Carbon atans,produced in the pyrolysis
Triphenylphosphine -iodine complex was found to be an effective reagent for deoxygenation of trisubstituted steroidal epoxides. The mechanism of the reaction is proposed.
Recent investigations have shown iron pentacarbonyl [Fe(CO)5] to be a useful reagent for effecting a variety of synthetic transformations.1 Non-polar solvents such as ethers have generally been employed for these reactions. In several cases, it has been demonstrated that reactions which do not take