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Trimethylsilyl group directed wagner-meerwein rearrangement of bicyclo[2.2.2]octan-2-ol derivatives

โœ Scribed by Morio Asaoka; Hisashi Takei

Publisher
Elsevier Science
Year
1987
Tongue
French
Weight
217 KB
Volume
28
Category
Article
ISSN
0040-4039

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โœฆ Synopsis

Trimethylsilyl group substituted bicyclo[Z.Z.Zloctane derivatives were synthesized and subjected to TMS group directed Wagner-Meerwein rearrangement to give bicyclo[3.2.lloctene derivatives in high yields.

In connection with projected total syntheses of some natural products utilizing 5-trimethylsilyl-2-cyclohexenone (l),')

we examined the synthesis of

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