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Trimethylaluminium promoted rearrangements of unsaturated sugars into cyclohexanes

✍ Scribed by Cai Jia; Alan J. Pearce; Yves Blériot; Yongmin Zhang; Li-He Zhang; Matthieu Sollogoub; Pierre Sinaÿ

Book ID
108283707
Publisher
Elsevier Science
Year
2004
Tongue
English
Weight
302 KB
Volume
15
Category
Article
ISSN
0957-4166

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The a,B-unsaturated ketones (l), (3), and (4) on treatment with sulfuric acid in acetic anhydride underwent molecular transformations yielding the products (5), (7) and (8), respectively.