Trimercurated acetaldehyde. The crystal structures of 2[OHg3CCHO]NO3 · HNO3 and [HOHg2(NO3Hg)CCHO]NO3
✍ Scribed by D. Grdenić; D. Matković-Čalogović; M. Sikirica
- Publisher
- Elsevier Science
- Year
- 1987
- Tongue
- English
- Weight
- 588 KB
- Volume
- 319
- Category
- Article
- ISSN
- 0022-328X
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## Abstract The oxidation of copper, zinc and nickel by N~2~O~5~ led, respectively, to turquoise‐coloured single crystals of (NO)Cu(NO~3~)~3~ [monoclinic, __P__2~1~/__m__, __Z__ = 2, __a__ = 465.90(5), __b__ = 1111.7(1), __c__ = 700.7(1) pm, __β__ = 100.70(2)°, __wR__~2~ = 0.0566], light‐yellow sin
## Abstract For Abstract see ChemInform Abstract in Full Text.
Metal Oxidation with N 2 O 5 : The Nitrosylium Nitrates (NO)Cu(NO 3 ) 3 , (NO)2[Zn(NO3)4] and (NO)6[Ni4(NO3)12](NO3)2•(HNO3). -N2O5 is prepared by reaction of fuming HNO3 with P4O10 and directly condensed on the metal powders. The crystal structures of the resulting title compounds are determined by
Flowing and static gas-phase samples of HNO3 in 0 2 and N2 were analyzed by long-path ultraviolethisible (TJV/VIS) spectroscopy to reveal the presence of both NO2 and NO3, the concentrations of which were calculated using differential absorption cross sections. NO2 is produced predominantly by the h