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Trigonal-Bipyramidal Geometry Induced by an External Water Ligand in a Sterically Hindered Iron Salen Complex, Related to the Active Site of Protocatechuate 3,4-Dioxygenase

โœ Scribed by Kurahashi, Takuya; Oda, Kenji; Sugimoto, Manabu; Ogura, Takashi; Fujii, Hiroshi

Book ID
118253743
Publisher
American Chemical Society
Year
2006
Tongue
English
Weight
292 KB
Volume
45
Category
Article
ISSN
0020-1669

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A Trigonal-Bipyramidal Ferric Aqua Compl
A Trigonal-Bipyramidal Ferric Aqua Complex with a Sterically Hindered Salen Ligand as a Model for the Active Site of Protocatechuate 3,4-Dioxygenase
โœ Hiroshi Fujii; Yasuhiro Funahashi ๐Ÿ“‚ Article ๐Ÿ“… 2002 ๐Ÿ› John Wiley and Sons ๐ŸŒ English โš– 109 KB ๐Ÿ‘ 2 views

Protocatechurate 3,4-dioxygenase (3,4-PCD) has been found in soil bacteria and is known to play a role in degrading aromatic molecules in nature. [1, 2] The enzyme is classified as an intradiol dioxygenase and cleaves catechol analogues bound to the iron(iii) site into aliphatic products with incorp