(Trifluoromethyl)fluorogermanates

✍ Scribed by Dr. David J. Brauer; Prof. Dr. Hans Bürger; Dr. Reint Eujen

• Book ID: 101551716
• Publisher: John Wiley and Sons
• Year: 1980
• Tongue: English
• Weight: 186 KB
• Volume: 19
• Category: Article
• ISSN: 0044-8249
• DOI: 10.1002/anie.198008361

✦ Synopsis

Germanates containing fluorine and trifluoromethyl ligands are generally accessible by the pathways shown below. In aqueous solution X^⊖^ (X = Cl, Br, I) in the starting compound can be quantitatively precipitated by Ag^⊕^. As expected, the ligand geometry is octahedral in the dianions, and trigonal‐bipyramidal in the monoanions.
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