Trifluoromethylation of α-Haloketones
✍ Scribed by Novák, Petr; Lishchynskyi, Anton; Grushin, Vladimir V.
- Book ID
- 115474275
- Publisher
- American Chemical Society
- Year
- 2012
- Tongue
- English
- Weight
- 410 KB
- Volume
- 134
- Category
- Article
- ISSN
- 0002-7863
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## Abstract The carbon chemical shifts of several series of α‐haloketones have been measured. Whereas the carbon carrying the halogens shows a regular downfield shift with increasing electronegativity of the substituents, the adjacent carbonyl carbon is shifted upfield by chlorine, bromine and iodi
An up-to-date treatise on heteroallylic halides (-haloketones, -haloaldehydes, and -haloimines). Presents recent research results concerning availability of the title compounds, their chemical properties and reactivity toward selected carbon, nitrogen, oxygen, and sulfur nucleophiles, and their role