Trifluoromethyl-Radical-Mediated Carbony
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Yoshitaka Uenoyama; Takahide Fukuyama; Keisuke Morimoto; Osamu Nobuta; Hidefumi
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Article
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2006
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John Wiley and Sons
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German
⚖ 144 KB
## Abstract The carbonylation of alkanes **1** under radical‐reaction conditions was examined by using ethynyl triflone **A** as the unimolecular chain‐transfer (UMCT) reagent. Good to moderate yields of ethynyl ketones **2** were prepared by means of this three‐component coupling reaction. Higher