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Trifluoroacetyltriphenylsilane as a potentially useful fluorine-containing building block. Preparation and its transformation into 2,2-difluoro enol silyl ethers

✍ Scribed by Fugiang Jin; Biao Jiang; Yuanyao Xu


Publisher
Elsevier Science
Year
1992
Tongue
French
Weight
223 KB
Volume
33
Category
Article
ISSN
0040-4039

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✦ Synopsis


The first example of perfluoroacylsilanes-trifluoroacetyltriphenylsilane was prepared in good yield and it has been converted into a series of 2,2-difluoro enol silyl ethers in almost quantitative yields by treatment with various organolithiums. Methods for the synthesis of fluorinated organics with fluorine atom(s)