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Trifluoroacetimidoyl lithium; generation and reaction with electrophiles

✍ Scribed by Hisayuki Watanabe; Fumio Yamashita; Kenji Uneyama

Book ID
104224999
Publisher
Elsevier Science
Year
1993
Tongue
French
Weight
267 KB
Volume
34
Category
Article
ISSN
0040-4039

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✦ Synopsis

Generation and nucleophilic reactions of a-trifluoromethyl carbanion would he a promising entry to the syntheses of trifluoromethylated compounds of which unique proper&s play an important role in medicinal and agricultural chemistries and material sciences.l)s 2) However, rapid elimination of fluoride anion from a-trifluoromethylated sp3 carbanion makes its nucleophilic carbon-carbon bond formation rather difficult.3)* 4) Whereas, a-trifluoromethylated ~$2 carbanions such as trifluoropropenyl carbanion (la)

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