Triesters of tris-(hydroxymethyl) phosphine oxide
β Scribed by M. Anteunis; M. Verzele; G. Dacremont
- Publisher
- Wiley (John Wiley & Sons)
- Year
- 2010
- Weight
- 263 KB
- Volume
- 74
- Category
- Article
- ISSN
- 0037-9646
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π SIMILAR VOLUMES
Treatment of tris(2-pyridyl)phosphine or tris(2-pyridyl)phosphine oxide with electrophiles such as chlorine, bromine, deuterium chloride, or benzenediazonium chloride gave unusual coupling products, i.e., 5-chloro-, 5-bromo-, 5-deuterio-, or 5-phenylazo-2,2Πbipyridyls, respectively, as a major coupl
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## Abstract The 1βheteroalkylation of the trisβ(trimethylsilyl)phosphine was thoroughly investigated using heterosubstituted methylamines, chloromethyl alkyl ethers, methyl chloroformate, paraformaldehyde, and dialkylformamides. Convenient methods for the synthesis of tris(dialkylaminomethyl)phosph