Tricyclohexylphosphine complexes of rhodium, iridium and ruthenium
β Scribed by Brian R. James; Michael Preece; Stephen D. Robinson
- Publisher
- Elsevier Science
- Year
- 1979
- Tongue
- English
- Weight
- 296 KB
- Volume
- 34
- Category
- Article
- ISSN
- 0020-1693
No coin nor oath required. For personal study only.
π SIMILAR VOLUMES
## Abstract A library of organometallic compounds derived from primary and secondary amines cyclometalated by ruthenium(II), rhodium(III) and iridiβ um(III) was tested in the asymmetric transfer hydrogenation of a number of ketones and imines. All compounds displayed high catalytic activity for the
The temperature variation of the solubility of hydrogen in rhodium, ruthenium, iridium and nickel in equilibrium with H,.gas at. 1 atm pressure has been measured by a technique involving saturating the solvent metal with hydrogen, quenching and analyzing in resultant solid solutions. The solubiliti