Tricyclo[5.1.0.02,8]oct-3-en, -oct-4-en und -octan: Darstellung und Thermolyse der Hydroderivate des Octavalens
✍ Scribed by Christl, Manfred ;Herzog, Clemens ;Kemmer, Petra
- Publisher
- Wiley (John Wiley & Sons)
- Year
- 1986
- Tongue
- English
- Weight
- 866 KB
- Volume
- 119
- Category
- Article
- ISSN
- 0009-2940
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## Abstract Tricyclo[3.2.1.0^2,7^]octan‐3‐ol (**1**) and its 4‐isomer **7** were obtained by hydroboration of tricyclo[3.2.1.0^2,7^]oct‐3‐ene (**5**). The former alcohol **1** is quantitatively converted to the isomeric alcohol __exo__‐bicyclo[3.2.1]oct‐2‐en‐7‐ol (**3**) by treatment with aqueous a
## Abstract Solvolyses of the 2,4‐dinitrobenzoates of the cyclopropylcarbinol **1a**, the cyclo‐butanol **2a** and the homoallylic alcohol **3a** in buffered 70% aqueous dioxane lead to the same product mixture consisting of 78% cyclopropylcarbinol **1a** and 22% homoallylic alcohol **3a**. Approxi