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Trichocarpinine, a Novel Hetidine–Hetisine Type Bisditerpenoid Alkaloid from Aconitum tanguticum var. trichocarpum

✍ Scribed by Ling Lin; Dong-Lin Chen; Xiao-Yu Liu; Qiao-Hong Chen; Feng-Peng Wang


Publisher
John Wiley and Sons
Year
2010
Tongue
German
Weight
166 KB
Volume
93
Category
Article
ISSN
0018-019X

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✦ Synopsis


Abstract

Trichocarpinine (1), the first hetidine–hetisine type bisditerpenoid alkaloid, was isolated from the whole herbs of Aconitum tanguticum var. trichocarpum. Its structure was determined by a combination of spectroscopic techniques, including HR‐ESI‐MS and 1D‐ and 2D‐NMR experiments. Its plausible biogenetic pathway was proposed as well (Scheme).