✦ LIBER ✦

Trichloroacetimidate as a Leaving Group in the Ferrier Rearrangement: Highly Stereoselective Synthesis of Pseudogalactal Glycosides

✍ Scribed by Adel A.-H. Abdel-Rahman; Gottfried A. Winterfeld; Mohamed Takhi; Richard R. Schmidt

Publisher: John Wiley and Sons
Year: 2002
Tongue: English
Weight: 294 KB
Volume: 2002
Category: Article
ISSN: 1434-193X
DOI: 10.1002/1099-0690(200202)2002:4<713::aid-ejoc713>3.0.co;2-q

No coin nor oath required. For personal study only.

✦ Synopsis

The Ferrier rearrangement of a galactal derivative 2 bearing the trichloroacetimidate functionality as a leaving group at the C-3 position was performed in the presence of trimethyl-