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Tricarbonyl rhenium(I) complex of benzothiazole – Synthesis, spectroscopic characterization, X-ray crystal structure and DFT calculations

✍ Scribed by Machura, B.; Wolff, M.; Benoist, E.; Coulais, Y.

Book ID: 118165884
Publisher: Elsevier Science
Year: 2013
Tongue: English
Weight: 443 KB
Volume: 724
Category: Article
ISSN: 0022-328X
DOI: 10.1016/j.jorganchem.2012.10.020

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The mononuclear complexes [Re(CO) 3 (Hpz) 2 Br] (1) and [Re(CO) 3 (py)(Hpz)(pz)] species (6). The analogues of 4 and 6 with Hdmpz, i.e. [Re(CO) 3 (Hdmpz) 2 (dmpz)] ( ) and [Re(CO) 3 (Hdmpz) 2 Br] (2) were obtained by treating [Re(CO) 5 Br] with pyrazole (Hpz) or 3,5-dimethylpyrazole [Re(CO) 3 (py)(H