β Scribed by S. D. Clymer; N. C. Morosoff; A. L. Crumbliss
No coin nor oath required. For personal study only.
The plasma polymerization of triallylphosphine in order to form a crosslinked polymer thin film is described. The plasma polymer thin film has been characterized and shown to contain a high proportion of C = C and P groups conserved from the monomer. The accessibility of the phosphine groups has been demonstrated by reaction with 0 2 , NO, Ni ( CO), , and Fe( CO ) 5 . Reaction with 0 2 and NO results in a P = 0 moiety formation.
Reaction with the gaseous metal carbonyls results in fixation of the metal via complexation by the P groups as a result of exchange with CO ligand( s ) . This illustrates the utility of a ligand donor group containing plasma polymer as an avenue for the formation of a single phase transition metal containing plasma polymer.
π SIMILAR VOLUMES
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