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Tri(1-cyclohepta-2,4,6-trienyl)phosphan-komplexe des rhodiums(I) und iridiums(I)

✍ Scribed by Max Herberhold; Kurt Bauer; Wolfgang Milius


Publisher
Elsevier Science
Year
1995
Tongue
English
Weight
266 KB
Volume
502
Category
Article
ISSN
0022-328X

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πŸ“œ SIMILAR VOLUMES


Molecular Structures of Mononuclear Rhod
✍ Max Herberhold; Wolfgang Milius; Stefan Eibl πŸ“‚ Article πŸ“… 1999 πŸ› John Wiley and Sons 🌐 German βš– 123 KB πŸ‘ 2 views

The olefinic phosphane P(C 7 H 7 ) 3 (5) behaves as a tetradentate tripod ligand in [RhCl{P(g 2 -C 7 H 7 ) 3 }] (6), using all 3 cyclohepta-2,4,6-trienyl substituents as g 2 -coordinating side-arms. Nucleophilic displacement of the one-electron chloro ligand by halides or pseudohalides to give [RhX{