✦ LIBER ✦

Trends for intensities of vibrational overtones in methane

✍ Scribed by Kenneth Fox

Publisher: Elsevier Science
Year: 1984
Tongue: English
Weight: 278 KB
Volume: 104
Category: Article
ISSN: 0009-2614
DOI: 10.1016/0009-2614(84)85297-5

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✦ Synopsis

The concept of local vibrational modes is examined quantitatively for spherical-top molecules. New theoretical formulations of transition electric dipole moments are developed for diatomics and local-mode spherical tops. Transition moments inferred from high-resolution spectra of va, 2va and 311s in '*CHQ and 13CH4 constitute the data base from which comparisons between theory and experiment, and predictions, are made.

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