Treatments of cross-termination rate constants in radical copolymerization
✍ Scribed by Ito, Katsukiyo
- Publisher
- Wiley (John Wiley & Sons)
- Year
- 1970
- Tongue
- English
- Weight
- 311 KB
- Volume
- 8
- Category
- Article
- ISSN
- 0449-296X
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📜 SIMILAR VOLUMES
## Abstract Rate constants for the self‐ and cross‐termination of the isopropylol radical [(CH~3~)~2~ĊOH] and its anion [(CH~3~)~2~ĊO^−^] in aqueous solution are determined by kinetic electron spin resonance. Whereas the self‐termination of the neutral radical occurs close to the diffusion‐controll
## Abstract The rate constant for the bimolecular combination of benzyl radicals in cyclohexane and toluene is determined as a function of temperature. Further, it is studied in cyclohexane–toluene mixtures of different compositions. In the entire range covered, 9.8 × 10^8^ ⩽ 2__k__~t~ ⩽ 9.0 × 10^9