Case I1 diffusion of penetrant liquids in polymer films is characterized by constant-velocity propagation of a phase interface. We review the development of viscoelastic models describing case I1 diffusion and then present a phase plane analysis for traveling wave solutions. For simplified, piecewi
β¦ LIBER β¦
Traveling waves for anomalous diffusion in polymers
β Scribed by S. Swaminathan; D.A. Edwards
- Book ID
- 104349654
- Publisher
- Elsevier Science
- Year
- 2004
- Tongue
- English
- Weight
- 345 KB
- Volume
- 17
- Category
- Article
- ISSN
- 0893-9659
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β¦ Synopsis
II diffusion of a penetrant through a polymer matrix is characterized by constant front speed. Hence, a traveling-wave analysis is appropriate for the model equations. For the previously validated model analyzed here, conditions on the molecular and stress diffusion coefficients are obtained which guarantee the existence of a traveling wave. Conditions are derived under which an interior maximum in the stress develops. An exact solution for the concentration and stress fields is derived for a special case.
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