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Trapping of the tribromomethylanion by electron poor alkenes

✍ Scribed by Mark S. Baird; Michele E. Gerrard; Robert J.G. Searle

Book ID
104236599
Publisher
Elsevier Science
Year
1985
Tongue
French
Weight
250 KB
Volume
26
Category
Article
ISSN
0040-4039

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✦ Synopsis

lost

in the final step,5 it may be expected to be less favoured in the case of displacement of halogen from a trihalomethyl-group. However, we now provide evidence for this mechanism in the case of bromoform reactions.

The presence of ester, nitrile or halogen substituents on an alkene is known to dramatically reduce the rate of reaction with dihalocarbenes generated by thermolysis of phenyl trihalomethyl mercuries.6 However, when ethyl or methyl a-bromoacrylates were treated with bromoform and 50% aq.

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