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Trapping of intermediate ions in a reaction related to the cope rearrangement

✍ Scribed by Donald C. Wigfield; Steve Feiner; Kevser Taymaz

Book ID
108383338
Publisher
Elsevier Science
Year
1972
Tongue
French
Weight
158 KB
Volume
13
Category
Article
ISSN
0040-4039

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📜 SIMILAR VOLUMES

A DFT Study on the Vinylcyclopropanecarb
A DFT Study on the Vinylcyclopropanecarbaldehyde-to-2,5-Dihydrooxepin Hetero-Cope-type Rearrangement and on Related Reactions
✍ Sperling, Dirk ;Reißig, Hans-Ulrich ;Fabian, Jürgen 📂 Article 📅 1997 🏛 John Wiley and Sons 🌐 English ⚖ 750 KB

## Abstract The prototypical 1,2‐__cis__‐vinylcyclopropanecarbaldehyde‐to‐2,5‐dihydrooxepin hetero‐Cope‐type rearrangement was studied by “exact” first‐principle methods. The reaction pathway was examined. The reaction, as well activation energies, was calculated for the unimolecular transformation