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Trapping of a cycloheptatetraene in the reaction of atomic carbon with phenol

✍ Scribed by Fatma Sevin; Ikay Sökmen; Bülent Düz; Philip B. Shevlin

Publisher
Elsevier Science
Year
2003
Tongue
French
Weight
102 KB
Volume
44
Category
Article
ISSN
0040-4039

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✦ Synopsis

Reaction of atomic carbon with phenol generates tropone in a reaction postulated to proceed via the hydroxycycloheptatetraenes, which rearrange to tropone. When the hydroxyphenylcarbenes are generated by the C atom deoxygenation of the corresponding aldehydes, the meta and para isomers produce tropone; the ortho isomer does not.

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