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Trapping of 1,4-diradical intermediate in intramolecular [2+2] photocycloaddition

✍ Scribed by D. Becker; N. Haddad; Y. Sahali

Publisher
Elsevier Science
Year
1989
Tongue
French
Weight
234 KB
Volume
30
Category
Article
ISSN
0040-4039

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✦ Synopsis

For the first time a 1,4-diradical intermediate u was trapped in 43% yield in an intramolecular [2+2] photocycloaddition of olefins to cyclohexenone. The results support the assumption that the first bond is formed to carbon-p of the enone system.

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