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Trapped ion photodissociation spectroscopy: the electronic spectrum of the hydrogen-bonded complex cation [C6H5OHN(CH3)3]+

✍ Scribed by Naohiko Mikami; Toshiki Sasaki; Shin Sato

Publisher: Elsevier Science
Year: 1991
Tongue: English
Weight: 425 KB
Volume: 180
Category: Article
ISSN: 0009-2614
DOI: 10.1016/0009-2614(91)85144-l

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✦ Synopsis

The electronic spectrum of the hydrogen-bonded complex cation, [C,HSOH-N(CHS),]+, has been observed by trapped ion photodissociation spectroscopy, in which the yield spectrum of the product ion H+N(CHI)s was acquired for the complex ion stored in a cylindrical ion trap cell. The spectrum in the range of 350-430 nm revealed that the stable complex cation has a structure composed of phenoxy radical and orotonatecl trimethylamine, that is, C&O-H+N (CH,),. The dissociation process of the photoionized complex was discussed.

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