The time-correlated single photon counting technique was applied to the measurement of photosensitized singlet oxygen luminescence induced by flash laser excitation. Rise and decay kinetics of this luminescence has been measured with 10 ns resolution in aqueous solutions of tetra(psulfophenyl)porphy
Trap levels in PbWO4 crystals: correlation with luminescence decay kinetics
โ Scribed by M. Martini; G. Spinolo; A. Vedda; M. Nikl; K. Nitsch; V. Hamplova; P. Fabeni; G.P. Pazzi; I. Dafinei; P. Lecoq
- Publisher
- Elsevier Science
- Year
- 1996
- Tongue
- English
- Weight
- 386 KB
- Volume
- 260
- Category
- Article
- ISSN
- 0009-2614
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โฆ Synopsis
X-ray excited luminescence, photoluminescence decay and thermally stimulated luminescence (TSL) measurements have been performed on a selected set of PbWO 4 single crystals. At room temperature the X-ray excited emission spectrum is characterized by two components peaking at about 2.5 and 3.1 eV. The photoluminescence decay indicates the presence of a slow recombination component extending up to a ms timescale and related mainly to the 2.5 eV emission. Different TSL peaks have been observed in the 100-300 K range: direct correlation has been found between integrated intensities of TSL peaks detected above 200 K, the intensity of the slow decay component and steady state emission intensity measured at 2.5 eV. These results suggest that thermal detrapping from TSL traps and free carrier diffusion followed by their radiative recombination at luminescent centers are responsible for the slow decay processes observed.
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