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Transsilylation reactions in esters and ethers of the silanols synthesis of oxasilacycloalkanes

✍ Scribed by V. F. Mironov; N. S. Fedotov; V. L. Kozlikov


Book ID
112378897
Publisher
Springer US
Year
1970
Tongue
English
Weight
218 KB
Volume
4
Category
Article
ISSN
0009-3122

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## Abstract The ethylaluminium dichloride induced reactions of methyl 10‐undecenoate (1) with dimethyl acetals of formaldehyde 2a, acetaldehyde 2b, isobutyraldehyde 2c, and pivaldehyde 2d gave the corresponding homoallyl ethers 3a, 3b, 3c, and 3d in yields of 48–70%. The products were obtained as m