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Transport properties and Mössbauer spectra of Fe-substituted La10−x(Si,Al)6O26 apatites

✍ Scribed by A.L. Shaula; V.V. Kharton; J.C. Waerenborgh; D.P. Rojas; E.V. Tsipis; N.P. Vyshatko; M.V. Patrakeev; F.M.B. Marques

Book ID
113785227
Publisher
Elsevier Science
Year
2004
Tongue
English
Weight
284 KB
Volume
39
Category
Article
ISSN
0025-5408

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Oxygen ionic and electronic transport in apatite-type La10−x(Si,Al)6O26±δ
✍ A.L. Shaula; V.V. Kharton; F.M.B. Marques 📂 Article 📅 2005 🏛 Elsevier Science 🌐 English ⚖ 755 KB

The main factor governing the oxygen ionic conductivity in apatite-type La 10Àx Si 6Ày Al y O 27À3x/2Ày/2 (x ¼ 020:33; y ¼ 0:521:5) is the concentration of mobile interstitials determined by the total oxygen content. The ion transference numbers, measured by modified faradaic efficiency technique, v