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Transport of small molecules in polyolefins. II. Diffusion and solubility of irganox 1076 in ethylene polymers

✍ Scribed by Enikő Földes

Publisher
John Wiley and Sons
Year
1993
Tongue
English
Weight
659 KB
Volume
48
Category
Article
ISSN
0021-8995

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Diffusion of small molecules in glassy p
Diffusion of small molecules in glassy polymers
✍ M. Pönitsch; P. Gotthardt; A. Grüger; H. G. Brion; R. Kirchheim 📂 Article 📅 1997 🏛 John Wiley and Sons 🌐 English ⚖ 255 KB 👁 2 views

Small molecules in glassy polymers are considered to occupy sites with a distribution of free energies of dissolution. Then their diffusivity depends on concentration and temperature in the same way as it has been derived for hydrogen atoms in metallic glasses. For hydrogen it was shown that the tra