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Transport of l-glutamic acid and l-glutamine and their incorporation into lenticular glutathione

โœ Scribed by H.L. Kern; C.-K. Ho


Book ID
115892758
Publisher
Elsevier Science
Year
1973
Tongue
English
Weight
608 KB
Volume
17
Category
Article
ISSN
0014-4835

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Asymmetric synthesis of L-[4-13C]glutami
โœ Kazuhiko Takatori; Takuya Sakamoto; Masahiro Kajiwara ๐Ÿ“‚ Article ๐Ÿ“… 2006 ๐Ÿ› John Wiley and Sons ๐ŸŒ French โš– 123 KB

l-[4-l3 C]Glutamic acid (1) and l-[4-13 C]glutamine (2) were synthesized from sodium [2-13 C]acetate (5) and Dellaria's oxazinone 3 as a chiral glycine equivalent. Sodium [2-13 C]acetate (5) was converted to [2-13 C]acrylate 4. Diastereoselective Michael addition of the enolate of 3 to the acrylate