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Transparent glass-ceramics doped with Cr(III): Low-temperature time-resolved spectra and characterization of gahnite and virgilite crystalline phases

✍ Scribed by Vincent Poncon; Joshua Kalisky; Georges Boulon; Renata Reisfeld


Publisher
Elsevier Science
Year
1987
Tongue
English
Weight
403 KB
Volume
133
Category
Article
ISSN
0009-2614

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✦ Synopsis


Trivalent chromium in transparent glass-ceramics (73.6 SiOl: 11.8 Alz0,:4.2 Li,O:7.0 ZnO: 1.6 TiOz: 1.5 Zr02:0.3 AszOl: 0.024 Cr203 mole%) enters mainly the gahnite phase after an equilibrium has been reached. The intermediate phase during heat treatment is of virgilite-type Li,AlSi,_,O,. This glass-ceramic has been studied by X-ray diffraction and time-resolved spectroscopy at low temperatures under laser excitation