cmaphthol crystallizes with the same type of hydrogen bonded chain like planar zig-zag structure as other X-H.-.X \_ systems (X = F. Cl. Br, and sometimes 0). The intramolecular k = 0 splitting for v(O-H) motions of crnaphthol has been clearly observed in the infrared spectrum with polarized light o
✦ LIBER ✦
Transmission window in the νs (OD) band of hydrogen-bonded monodeuteromethanol
✍ Scribed by J. Bournay; G.N. Robertson
- Publisher
- Elsevier Science
- Year
- 1979
- Tongue
- English
- Weight
- 294 KB
- Volume
- 60
- Category
- Article
- ISSN
- 0009-2614
No coin nor oath required. For personal study only.
✦ Synopsis
A study of the temperature evohtion of the vs(OD) band of self-assuciated CHjOD in solution shows cka.dy that the structure in this band is due to Fermi resonance with an infrared inactive overtone or combination. The degree of mismatch between tbe two interfering modes can be varied continuously over a substantial Frequency raixge simply by changing the temperature-I _ Introduction
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