✦ LIBER ✦
Transmetalation reactions of higher order cyanocuprates: Direct formation of trialkyltin cuprates from tin hydrides which bypasses organolithium intermediates
✍ Scribed by Bruce H. Lipshutz; Edmund L. Ellsworth; Stuart H. Dimock; Deborah C. Reuter
- Book ID
- 104244796
- Publisher
- Elsevier Science
- Year
- 1989
- Tongue
- French
- Weight
- 206 KB
- Volume
- 30
- Category
- Article
- ISSN
- 0040-4039
No coin nor oath required. For personal study only.
✦ Synopsis
Simple exposure of n-Bu3SnH to Bu2Cu(CN)Li2 in THF at low temperatures leads directly to the presumed mixed higher order trialkyltin cuprate, the reactions of which selectively transfer the trialkylstannyl group to a variety of substrates.