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Transmetalation of Z -Telluroenynes: Stereoselective Synthesis of Z -Enynols and Their Application in Palladium-Catalyzed Cyclization

✍ Scribed by Schneider, Caroline C.; Caldeira, Helton; Gay, Bibiana M.; Back, Davi F.; Zeni, Gilson


Book ID
121001643
Publisher
American Chemical Society
Year
2010
Tongue
English
Weight
399 KB
Volume
12
Category
Article
ISSN
1523-7060

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A stereoselective and flexible synthesis of various E-and Z-1,1-diaryl and triarylolefins 3 was achieved from readily available vinylstannanes 1 via stereospecific iodo-destannylation and subsequent palladium-catalyzed Negishi-type cross-coupling reaction with arylzinc reagents under mild conditions