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Transition structures of the Lewis acid-catalyzed Diels-Alder reaction of butadiene with acrolein. The origins of selectivity

✍ Scribed by Birney, David M.; Houk, K. N.

Book ID
120429371
Publisher
American Chemical Society
Year
1990
Tongue
English
Weight
805 KB
Volume
112
Category
Article
ISSN
0002-7863

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📜 SIMILAR VOLUMES

On the mechanism of Diels—Alder reaction
On the mechanism of Diels—Alder reactions catalyzed by Lewis acids
✍ V. Branchadell; A. Oliva; J. Bertran 📂 Article 📅 1985 🏛 Elsevier Science 🌐 English ⚖ 261 KB

The effect of Lewis acid catalysts on the mechanism of Diels-Alder reactions is studied using the MINDO/3 method. It is found that they tend to increase the two-step character of the process through a more important participation of the charge-transfer configuration.