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Transition structures for the stepwise insertion of oxygen into alkane tertiary CH bonds by dimethyldioxirane

✍ Scribed by Mauro Freccero; Remo Gandolfi; Mirko Sarzi-Amadè; Augusto Rastelli


Publisher
Elsevier Science
Year
2001
Tongue
French
Weight
127 KB
Volume
42
Category
Article
ISSN
0040-4039

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Activation of dithioformate by iron comp
✍ Dilip V. Khasnis; Nadine Pirio; Daniel Touchard; Loïc Toupet; Pierre H. Dixneuf 📂 Article 📅 1992 🏛 Elsevier Science 🌐 English ⚖ 896 KB

BH, containing iron complexes Fe(q'-HB(H),SCHSR')(CO)(PR,), (3) were prepared by reduction of Fe(q'-CS,R')(X)(CO)(PR& derivatives (2) with NaBH,. The X-ray structure of 3a (R' = R = Me) shows the cis addition of the H-and BH, fragments to the coordinated dithioformate C-S bond and that one B-H bond