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Transition-Metal Variation as a Probe of the Origins of Hypoelectronic Metallaboranes: Eight- and Ten-Vertex Open Ruthenaboranes

✍ Scribed by Sundargopal Ghosh; Alicia M. Beatty; Thomas P. Fehlner

Book ID
101527801
Publisher
John Wiley and Sons
Year
2003
Tongue
English
Weight
142 KB
Volume
115
Category
Article
ISSN
0044-8249

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Transition-Metal Variation as a Probe of
Transition-Metal Variation as a Probe of the Origins of Hypoelectronic Metallaboranes: Eight- and Ten-Vertex Open Ruthenaboranes
✍ Sundargopal Ghosh; Alicia M. Beatty; Thomas P. Fehlner πŸ“‚ Article πŸ“… 2003 πŸ› John Wiley and Sons 🌐 English βš– 143 KB

Scheme 1. Stepwise conversion of 1 into [(Cp\*RuH 2 ) 2 B 6 H 8 ] (4), [(Cp\*Ru) 2 B 8 H 12 ] (5), and [(Cp\*RuCO) 2 B 6 H 8 ] (6). Conditions: a) 608, BH 3 β€’THF; b) 908; c) 958, BH 3 β€’THF; d) 558, [Co 2 (CO) 8 ]. The structures shown are schematic representations, Γ€HΓ€ indicates an H-bridged bond.