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Transition-metal template synthesis of a rotaxane incorporating two different coordinating units in its thread

✍ Scribed by Pabio Gaviña; Jean-Pierre Sauvage

Book ID: 104257041
Publisher: Elsevier Science
Year: 1997
Tongue: French
Weight: 202 KB
Volume: 38
Category: Article
ISSN: 0040-4039
DOI: 10.1016/s0040-4039(97)00678-3

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✦ Synopsis

A [2]

rotaxane consisting of a molecular string threaded into a coordinating ring by means of the mmplate effect of copper (I) has been synthesized. The acyclic fragment in~tes two different chelating sites (bidentate and terdentate ligands) whereas the macroeycle bears a bidentate chelate. Two bulky groups have been covalently attached at the ends of the thread.

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