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Transition metal salts of heteropoly acids as palladium co-catalysts for Wacker oxidation of butene-1 to MEK

✍ Scribed by K. Nowinèska; M. Sopa; D. Dudko; M. Mocna


Book ID
110383020
Publisher
Springer US
Year
1997
Tongue
English
Weight
223 KB
Volume
49
Category
Article
ISSN
1011-372X

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Palladium salts of heteropolyanions as c
✍ A.W. Stobbe-Kreemers; M. van der Zon; M. Makkee; J.J.F. Scholten 📂 Article 📅 1996 🏛 Elsevier Science 🌐 English ⚖ 526 KB

Palladium salts of heteropolyanions, of the Keggin-series H3+ nPVnMol2\_nO40, supported on silica, have been successfully applied as catalysts in the gas-phase Wacker oxidation of 1-butene. In such catalysts the palladium reaction centre (Pd 2+ ) and the redox component (HPA) are combined in one com