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Transition Metal Oxide Work Functions: The Influence of Cation Oxidation State and Oxygen Vacancies

✍ Scribed by Mark T. Greiner; Lily Chai; Michael G. Helander; Wing-Man Tang; Zheng-Hong Lu


Book ID
111992232
Publisher
John Wiley and Sons
Year
2012
Tongue
English
Weight
676 KB
Volume
22
Category
Article
ISSN
1616-301X

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O-vacancies in transition metal (TM) oxi
✍ G. Lucovsky; D. Zeller; J.L. Whitten πŸ“‚ Article πŸ“… 2011 πŸ› Elsevier Science 🌐 English βš– 471 KB

Removal of neutral O-atoms from a transition metal (TM) oxide results in two electrons residing within the vacated site. Two-electron multiplet theory has been used to develop a d 2 equivalent model. When applied to tetragonal HfO 2 , the two electrons of neutral vacancy in the d 2 equivalent limit