Transition Metal Methylene Complexes, XXVII. Synthesis of the First Heavy-Metal Substituted μ-Methylene Complex
✍ Scribed by Herrmann, Wolfgang A. ;Huggins, John M.
- Publisher
- Wiley (John Wiley & Sons)
- Year
- 1982
- Tongue
- English
- Weight
- 185 KB
- Volume
- 115
- Category
- Article
- ISSN
- 0009-2940
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📜 SIMILAR VOLUMES
**Surprising reactions of carbon monoxide with transition metal complexes** have been observed with compounds __(1)__ and __(2)__. The carbyne complex __(1)__ takes up CO at normal pressure and −30°C to form the metalated ketene __(2)__ which itself is deoxygenated by CO at +60°C and under 60atm pre
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