Transition Metal Ions: Charge Carriers that Mediate the Electron Capture Dissociation Pathways of Peptides

Transition metals as electron traps. I.

Transition metals as electron traps. I. Structures, energetics, electron capture, and electron-transfer-induced dissociations of ternary copper–peptide complexes in the gas phase

✍ František Tureček; Jace W. Jones; Anne I. S. Holm; Subhasis Panja; Steen Brøndst 📂 Article 📅 2009 🏛 John Wiley and Sons 🌐 English ⚖ 680 KB

## Abstract Electron‐induced dissociations of gas‐phase ternary copper‐2,2′‐bipyridine complexes of Gly‐Gly‐Gly and Gly‐Gly‐Leu were studied on a time scale ranging from 130 ns to several milliseconds using a combination of charge‐reversal (^+^CR^−^) and electron‐capture‐induced dissociation (ECID)